Output details
15 - General Engineering
University of South Wales
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Article title
Kubas-Type Hydrogen Storage in V(III) Polymers Using Tri- and Tetradentate Bridging Ligands
Type
D - Journal article
Title of journal
Journal of the American Chemical Society
Article number
-
Volume number
133
Issue number
13
First page of article
4955
ISSN of journal
1520-5126
Year of publication
2011
URL
-
Number of additional authors
5
Additional information
This paper describes a one-dimensional Vanadium polymer that binds hydrogen by the Kubas interaction. The major breakthrough is that this new material, replaces hydrazine (used in paper 2) with oxamide, a safer alternative. Similar activities as observed in paper 2 are achieved with greater safety. Also the first unequivocal spectroscopic evidence of Kubas binding in the framework of an extended solid is also provided, proving the adsorption mechanism described in papers 1 and 2, while also demonstrating for the first time that the Kubas interaction is not limited to molecular systems.
Interdisciplinary
-
Cross-referral requested
-
Research group
2 - Sustainable Environment Research Centre
Proposed double-weighted
No
Double-weighted statement
-
Reserve for a double-weighted output
No
Non-English
No
English abstract
-