Output details

Access to enhanced differences in Marcus–Hush and

Butler–Volmer electron transfer theories by systematic analysis of higher order AC harmonics

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The latest in a series of 16 papers Gavaghan has published with Alan Bond at Monash. This work establishes a novel electroanalytical technique, AC voltammetry, providing access to a range of electrochemical reactions not accessible by previous techniques; several groups across the world have adopted and use this technique. Gavaghan’s group has been responsible for development of all underpinning mathematical and computational theory. This paper describes the extension of our theoretical work to include Marcus-Hush theory and thereby extend the range of applicability of the technique.