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15 - General Engineering

University of South Wales

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Output 29 of 53 in the submission

Article title

Kubas-Type Hydrogen Storage in V(III) Polymers Using Tri- and Tetradentate Bridging Ligands

Type

D - Journal article

DOI

10.1021/ja110243r

Title of journal

Journal of the American Chemical Society

Article number

Volume number

133

Issue number

First page of article

4955

ISSN of journal

1520-5126

Year of publication

2011

URL

Number of additional authors

Additional information

This paper describes a one-dimensional Vanadium polymer that binds hydrogen by the Kubas interaction. The major breakthrough is that this new material, replaces hydrazine (used in paper 2) with oxamide, a safer alternative. Similar activities as observed in paper 2 are achieved with greater safety. Also the first unequivocal spectroscopic evidence of Kubas binding in the framework of an extended solid is also provided, proving the adsorption mechanism described in papers 1 and 2, while also demonstrating for the first time that the Kubas interaction is not limited to molecular systems.

Interdisciplinary

Cross-referral requested

Research group

2 - Sustainable Environment Research Centre

Proposed double-weighted

Double-weighted statement

Reserve for a double-weighted output

Non-English

English abstract