Output details
15 - General Engineering
University of South Wales
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Article title
Design and Synthesis of Vanadium Hydrazide Gels for Kubas-Type Hydrogen Adsorption: A New Class of Hydrogen Storage Materials
Type
D - Journal article
Title of journal
Journal of the American Chemical Society
Article number
-
Volume number
132
Issue number
33
First page of article
11792
ISSN of journal
1520-5126
Year of publication
2010
URL
-
Number of additional authors
6
Additional information
This paper describes a vanadium hydrazide gel, the first example of a solid state material in which the Kubas interaction is the principle means of hydrogen storage, thus creating a new catagory for hydrogen storage solids distinct from physisorption and hydrides. The reversible volumetric activities are also the highest observed at 77 K for any porous material - surpassing metal organic frameworks (MOFs) by 60% - with retentions at 298 K of performance of 30%, comparing to 10% for MOFs. Because of this paradigm-shifting breakthrough it was the focus of a feature article by Geoff Ozin in Materials Views.
Interdisciplinary
-
Cross-referral requested
-
Research group
2 - Sustainable Environment Research Centre
Proposed double-weighted
No
Double-weighted statement
-
Reserve for a double-weighted output
No
Non-English
No
English abstract
-
